彼奥尼是徐利亚的一名司祭。在德西乌斯在位期间，彼奥尼在斯密尔纳遭受了迫害，被判处钉在十字架上，为此，彼奥尼却感到非常欣喜。当士兵们预备好了十字架放在地上的时候，彼奥尼心甘情愿地躺上去，自动地将手臂放在十字架上，叫士兵们拿长钉来钉他。十字架被头朝下脚朝上地插入到土中，并在彼奥尼的头下生起了火，许多人在那里围观。彼奥尼闭上了眼睛内心向上帝祷告。火苗却丝毫没有烧损他的头发。最后火苗熄灭了，人们认为彼奥尼已经死了，但是他却睁开了眼睛，欣喜若狂地惊呼道：“上帝啊，请接收我的灵魂！”，然后就断气了。这位圣人书写了《斯密尔纳的圣颇利卡尔普的生活》，如今在天国中，他可以同这位圣人同享天国之乐。彼奥尼于公元250年荣耀殉道。 
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